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Long-lasting Solid-state Lithium Battery From Harvard May Solve a 40-year Problem

Long-lasting, quick-charging batteries are essential to the expansion of the electric vehicle market, but today’s lithium-ion batteries fall short of what’s needed — they’re too heavy, too expensive and take too long to charge.

lithium battery experiment – courtesy of Second Bay Studios:Harvard SEAS

For decades, researchers have tried to harness the potential of solid-state, lithium-metal batteries, which hold substantially more energy in the same volume and charge in a fraction of the time compared to traditional lithium-ion batteries.

“A lithium-metal battery is considered the holy grail for battery chemistry because of its high capacity and energy density,” said Xin Li, Associate Professor of Materials Science at the Harvard John A. Paulson School of Engineering and Applied Science (SEAS). “But the stability of these batteries has always been poor.”

Now, Li and his team have designed a stable, lithium-metal solid state battery that can be charged and discharged at least 10,000 times — far more cycles than have been previously demonstrated — at a high current density. The researchers paired the new design with a commercial high energy density cathode material.

This battery technology could increase the lifetime of electric vehicles to that of the gasoline cars — 10 to 15 years — without the need to replace the battery. With its high current density, the battery could pave the way for electric vehicles that can fully charge within 10 to 20 minutes.

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“Our research shows that the solid-state battery could be fundamentally different from the commercial liquid electrolyte lithium-ion battery,” said Li. “By studying their fundamental thermodynamics, we can unlock superior performance and harness their abundant opportunities.”

The big challenge with lithium-metal batteries has always been chemistry. Lithium batteries move lithium ions from the cathode to the anode during charging. When the anode is made of lithium metal, needle-like structures called dendrites form on the surface. These structures grow like roots into the electrolyte and pierce the barrier separating the anode and cathode, causing the battery to short or even catch fire.

To overcome this challenge, Li and his team designed a multilayer battery that sandwiches different materials of varying stabilities between the anode and cathode. This multilayer, multimaterial battery prevents the penetration of lithium dendrites not by stopping them altogether but rather by controlling and containing them.

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Like a BLT sandwich

Think of the battery like a BLT sandwich. First comes the bread — the lithium metal anode — followed by lettuce — a coating of graphite. Next, a layer of tomatoes — the first electrolyte — and a layer of bacon — the second electrolyte. Finish it off with another layer of tomatoes and the last piece of bread — the cathode.

Courtesy of Second Bay Studios : Harvard SEAS

The first electrolyte (chemical name Li5.5PS4.5Cl1.5 or LPSCI) is more stable with lithium but prone to dendrite penetration. The second electrolyte, (Li10Ge1P2S12 or LGPS) is less stable with lithium but appears immune to dendrites. In this design, dendrites are allowed to grow through the graphite and first electrolyte but are stopped when they reach the second. In other words, the dendrites grow through the lettuce and tomato but stop at the bacon. The bacon barrier stops the dendrites from pushing through and shorting the battery.

“Our strategy of incorporating instability in order to stabilize the battery feels counterintuitive but just like an anchor can guide and control a screw going into a wall, so too can our multilayer design guide and control the growth of dendrites,” said Luhan Ye, co-author of the paper and graduate student at SEAS.

“The difference is that our anchor quickly becomes too tight for the dendrite to drill through, so the dendrite growth is stopped,” Li added.

The battery is also self-healing; its chemistry allows it to backfill holes created by the dendrites.

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“This proof-of-concept design shows that lithium-metal solid-state batteries could be competitive with commercial lithium-ion batteries,” said Li. “And the flexibility and versatility of our multilayer design makes it potentially compatible with mass production procedures in the battery industry. Scaling it up to the commercial battery wont’ be easy and there are still some practical challenges, but we believe they will be overcome.”

The research was published in Nature, and supported by Dean’s Competitive Fund for Promising Scholarship at Harvard University and Harvard Data Science Initiative Competitive Research Fund.

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