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Researchers develop new metal-free, recyclable polypeptide battery that degrades on demand

The introduction of lithium-ion (Li-ion) batteries has revolutionized technology as a whole, leading to major advances in consumer goods across nearly all sectors. Battery-powered devices have become ubiquitous across the world. While the availability of technology is generally a good thing, the rapid growth has led directly to several key ethical and environmental issues surrounding the use of Li-ion batteries.

Current Li-ion batteries utilize significant amounts of cobalt, which in several well-documented international cases is mined using child labor in dangerous working environments. Additionally, only a very small percentage of Li-ion batteries are recycled, increasing the demand for cobalt and other strategic elements.

A multidisciplinary team of researchers from Texas A&M University has made a breakthrough that could lead to battery production moving away from cobalt. In an article published in the May issue of Nature, Dr. Jodie Lutkenhaus, Axalta Coating Systems Chair and professor in the Artie McFerrin Department of Chemical Engineering, and Dr. Karen Wooley, distinguished professor in the Department of Chemistry and holder of the W.T. Doherty-Welch Chair in Chemistry in the College of Science, outline their research into a new battery technology platform that is completely metal free. This new battery technology platform utilizes a polypeptide organic radical construction.

“By moving away from lithium and working with these polypeptides, which are components of proteins, it really takes us into this realm of not only avoiding the need for mining precious metals, but opening opportunities to power wearable or implantable electronic devices and also to easily recycle the new batteries,” said Wooley, recently honored as the 2021 SEC Professor of the Year. “They [polypeptide batteries] are degradable, they are recyclable, they are non-toxic and they are safer across the board.”

The all-polypeptide organic radical battery composed of redox-active amino-acid macromolecules also solves the problem of recyclability. The components of the new battery platform can be degraded on demand in acidic conditions to generate amino acids, other building blocks and degradation products — one of the major breakthroughs in this research, according to Lutkenhaus.

“The big problem with lithium-ion batteries right now is that they’re not recycled to the degree that we are going to need for the future electrified transportation economy,” Lutkenhaus added. “The rate of recycling lithium-ion batteries right now is in the single digits. There is valuable material in the lithium-ion battery, but it’s very difficult and energy intensive to recover.”

The development of a metal-free, all-polypeptide organic radical battery composed of redox-active amino-acid macromolecules that degrade on demand marks significant progress toward sustainable, recyclable batteries that minimize dependence on strategic metals. As a next step, Wooley and Lutkenhaus have begun working in collaboration with Dr. Daniel Tabor, assistant professor in the Department of Chemistry, through a 2020 Texas A&M Triads for Transformation (T3) grant that aims to utilize machine learning to optimize the materials and structure of the battery platform.

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The lead authors on the paper are Tan Nguyen, a current postdoctoral associate at the University of Michigan and former doctoral student from the Texas A&M Department of Chemistry, and Alexandra Easley, a doctoral student in the Department of Materials Science and Engineering at Texas A&M.

This work was financially supported by the National Science Foundation, the Welch Foundation and the U.S. Department of Energy Office of Science.

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